An Isolated Nitridyl Radical-Bridged {Rh(N-center dot)Rh} Complex
2014 | journal article. A publication with affiliation to the University of Göttingen.
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An Isolated Nitridyl Radical-Bridged {Rh(N-center dot)Rh} Complex
Gloaguen, Y.; Rebreyend, C.; Lutz, M.; Kumar, P.; Huber, M.; van der Vlugt, J. I. & Schneider, S. et al. (2014)
Angewandte Chemie International Edition, 53(26) pp. 6814-6818. DOI: https://doi.org/10.1002/anie.201403445
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Details
- Authors
- Gloaguen, Yann; Rebreyend, Christophe; Lutz, Martin; Kumar, Pravin; Huber, Martina; van der Vlugt, Jarl Ivar; Schneider, Sven; de Bruin, Bas
- Abstract
- Photochemical activation of [(PNNH)Rh(N-3)] (PNNH=6-di-(tert-butyl)phosphinomethyl-2,2'-bipyridine) complex 2 produced the paramagnetic (S = 1/2), [(PNN) Rh= N-center dot-Rh(PNN)] complex 3 (PNN = = methylene-deprotonated PNNH), which could be crystallographically characterized. Spectroscopic investigation of 3 indicates a predominant nitridyl radical (N-center dot(2-)) character, which was confirmed computationally. Complex 3 reacts selectively with CO, producing two equivalents of [(PNN)Rh-I(CO)]complex 4, presumably by nitridyl radical N, N-coupling.
- Issue Date
- 2014
- Status
- published
- Publisher
- Wiley-v C H Verlag Gmbh
- Journal
- Angewandte Chemie International Edition
- ISSN
- 1521-3773; 1433-7851
