Dinitrogen Splitting and Functionalization in the Coordination Sphere of Rhenium
2014 | journal article. A publication with affiliation to the University of Göttingen.
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Details
- Authors
- Klopsch, Isabel; Finger, Markus ; Wuertele, Christian; Milde, Bastian; Werz, Daniel B.; Schneider, Sven
- Abstract
- [ReCl3(PPh3)(2)(NCMe)] reacts with pincer ligand HN(CH2CH2PtBu2)(2) (HPNP) to five coordinate rhenium(III) complex [ReCl2(PNP)]. This compound cleaves N-2 upon reduction to give rhenium(V) nitride [Re(N)Cl(PNP)], as the first example in the coordination sphere of Re. Functionalization of the nitride ligand derived from N-2 is demonstrated by selective C N bond formation with MeOTf.
- Issue Date
- 2014
- Status
- published
- Publisher
- Amer Chemical Soc
- Journal
- Journal of the American Chemical Society
- ISSN
- 0002-7863
- Sponsor
- DFG programs; Heisenberg programs; FCI
