Synthesis and structural characterization of gallium and indium complexes obtained from redistribution reactions of mixed chalcogen-imidodiphosphinate ligands
2005 | journal article. A publication with affiliation to the University of Göttingen.
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Synthesis and structural characterization of gallium and indium complexes obtained from redistribution reactions of mixed chalcogen-imidodiphosphinate ligands
Moya-Cabrera, M.; Cea-Olivares, R.; Alcántara-García, J.; Toscano, R. A.; Jancik, V. ; García-Montalvo, V. & Hernández-Ortega, S. (2005)
Journal of Organometallic Chemistry, 690(12) pp. 3054-3060. DOI: https://doi.org/10.1016/j.jorganchem.2005.03.042
Documents & Media
Details
- Authors
- Moya-Cabrera, Mónica; Cea-Olivares, Raymundo; Alcántara-García, Jocelyn; Toscano, Rubén A.; Jancik, Vojtech ; García-Montalvo, Verónica; Hernández-Ortega, Simón
- Abstract
- The ionic complex [Ga{N(SP'Pr(2))(SeP'Pr(2))-S, Se}(2)](+)[GaCl(4)](-) (5) was prepared by a ligand redistribution process from the monochelate Cl(2)Ga{N(SP'Pr(2))(SeP'Pr(2))-S,Se}] (3) complex in benzene. A similar phenomenon was observed for the heavier indium homologues, where the neutral complexes [ClIn{N(SP'Pr(2))(SeP'Pr(2))-S, Se}(2)] (7) and [ClIn{N(OP'Pr(2))(SP'Pr(2))-O, S}(2)] (8) were isolated along with InCl(3) as the main reaction by-product. Complexes 5, 7 and 8 were characterized by single-crystal X-ray structural analysis. (c) 2005 Elsevier B.V. All rights reserved.
- Issue Date
- 2005
- Journal
- Journal of Organometallic Chemistry
- ISSN
- 0022-328X
- Language
- English
