Monomeric siliconthiodichloride trapped by a Lewis base
2015 | journal article. A publication with affiliation to the University of Göttingen.
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- Authors
- Roy, Sudipta; Mondal, Kartik Chandra; Mondal, Totan; Koley, Debasis; Dittrich, Birger; Roesky, Herbert W.
- Abstract
- Thiophosgene (CSCl2), a chemical reagent used in numerous organic syntheses, exists in the monomeric form while its heavier silicon analogue [siliconthiodichloride (SiSCl2)] has been isolated so far as a dimer at room temperature and as a tetramer at 180 degrees C. Herein, we report on the first synthesis, isolation, and characterization of cyclic alkyl(amino) carbene (cAAC) stabilized siliconthiodichloride (cAAC) SiSCl2 (3) in the neutral monomeric form. 3 is synthesized via reaction of (cAAC(center dot))(2)Si2Cl4 (1) or (cAAC)(2)Si2Cl2 (2) with S-8 in the temperature range of -78 to 20 degrees C. An NHC [NHC = N-heterocyclic carbene] analogue of 3 is not isolated when (NHC) SiCl2 is reacted with S-8. The bright yellow colored compound 3 is soluble in polar organic solvents. It is stable at room temperature for a month under an inert atmosphere. 3 decomposes above 160 degrees C. The monomeric molecular structure of 3 has been unambiguously confirmed by X-ray single crystal diffraction. 3 is also characterized by NMR, UV-vis, and IR spectroscopy. The bonding and electron density distributions of 3 have been further studied by theoretical calculations.
- Issue Date
- 2015
- Status
- published
- Publisher
- Royal Soc Chemistry
- Journal
- Dalton Transactions
- ISSN
- 1477-9234; 1477-9226