Organotrifluoroborates as attractive self-assembling systems: the case of bifunctional dipotassium phenylene-1,4-bis(trifluoroborate)
2015 | journal article. A publication with affiliation to the University of Göttingen.
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Organotrifluoroborates as attractive self-assembling systems: the case of bifunctional dipotassium phenylene-1,4-bis(trifluoroborate)
Falcicchio, A.; Lill, S. O. N.; Perna, F. M.; Salomone, A.; Coppi, D. I.; Cuocci, C. & Stalke, D. et al. (2015)
Dalton Transactions, 44(45) pp. 19447-19450. DOI: https://doi.org/10.1039/c5dt02020d
Documents & Media
Details
- Authors
- Falcicchio, Aurelia; Lill, Sten O. Nilsson; Perna, Filippo M.; Salomone, Antonio; Coppi, Donato I.; Cuocci, Corrado; Stalke, Dietmar; Capriati, Vito
- Abstract
- The first structure of an aromatic bis(trifluoroborate) dipotassium salt, elucidated by the combination of crystallography, DFT calculations, topological and non-covalent interaction analysis, discloses a 3D network undergoing spontaneous self-assembly thanks to the massive participation of weak intra- and intermolecular interactions for which fluorine atoms proved to play a leading role.
- Issue Date
- 2015
- Status
- published
- Publisher
- Royal Soc Chemistry
- Journal
- Dalton Transactions
- ISSN
- 1477-9234; 1477-9226
