Electron-rich, Nitrido-bridged Ruthenium Complexes
2015 | journal article. A publication with affiliation to the University of Göttingen.
Jump to: Cite & Linked | Documents & Media | Details | Version history
Cite this publication
Electron-rich, Nitrido-bridged Ruthenium Complexes
Glueer, A.; Askevold, B.; Schluschass, B.; Heinemann, F. W. & Schneider, S. (2015)
Zeitschrift für anorganische und allgemeine Chemie, 641(1) pp. 49-51. DOI: https://doi.org/10.1002/zaac.201400166
Documents & Media
Details
- Authors
- Glueer, Arne; Askevold, Bjorn; Schluschass, Bastian; Heinemann, Frank W.; Schneider, Sven
- Abstract
- Terminal Ru-IV nitride [RuN{N(CH2CH2PtBu2)(2)}] (1) and [RuCl{N(CH2CH2PtBu2)(2)}] (2a) form an equilibrium with bridging nitride [{(tBu(2)PCH(2)CH(2))(2)N} Ru(mu-N) RuCl{N(CH2CH2PtBu2)(2)}] (3a). While 3a could only be spectroscopically characterized yet not isolated, the reaction of the divinylamido chloro complex [RuCl{N(CHCHPtBu2)(2)}] (2b) with half an equivalent azide directly gave the analogous bridging nitride [{(tBu(2)PCHCH)(2)N} Ru(mu N) RuCl{N(CHCHPtBu2)(2)}] (3b), which was isolated and fully characterized.
- Issue Date
- 2015
- Status
- published
- Publisher
- Wiley-v C H Verlag Gmbh
- Journal
- Zeitschrift für anorganische und allgemeine Chemie
- ISSN
- 1521-3749; 0044-2313
- Sponsor
- Deutsche Forschungsgemeinschaft
