C-H-activated aluminum hydroxide via molecular oxygen

2006 | journal article. A publication with affiliation to the University of Göttingen.

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​C-H-activated aluminum hydroxide via molecular oxygen​
Li, X. F.; Song, H. B.; Duan, L. L.; Cui, C. M. & Roesky, H. W.​ (2006) 
Inorganic Chemistry, 45(5) pp. 1912​-1914​.​ DOI: https://doi.org/10.1021/ic0600230 

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Authors
Li, X. F.; Song, H. B.; Duan, L. L.; Cui, C. M.; Roesky, H. W.
Abstract
The reaction of LAl[eta(2)-(C-2(SiMe3)(2))] (1; L = HC[(CMe)(NDipp)](2), Dipp = 2,6-iPr(2)C(6)H(3)) with dioxygen leads to the elimination of bis(trimethylsilyl)acetylene and the formation of the corresponding aluminum monohydroxide via the oxidation of one of the CHMe2 groups on the Dipp ring.
Issue Date
2006
Status
published
Publisher
Amer Chemical Soc
Journal
Inorganic Chemistry 
ISSN
0020-1669

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