Water oxidation catalyzed by molecular di- and nonanuclear Fe complexes: importance of a proper ligand framework

2016 | journal article. A publication with affiliation to the University of Göttingen.

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​Water oxidation catalyzed by molecular di- and nonanuclear Fe complexes: importance of a proper ligand framework​
Das, B.; Lee, B.-L.; Karlsson, E. A.; Akermark, T.; Shatskiy, A.; Demeshko, S. & Liao, R.-Z. et al.​ (2016) 
Dalton Transactions45(34) pp. 13289​-13293​.​ DOI: https://doi.org/10.1039/c6dt01554a 

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Authors
Das, Biswanath; Lee, Bao-Lin; Karlsson, Erik A.; Akermark, Torbjorn; Shatskiy, Andrey; Demeshko, Serhiy; Liao, Rong-Zhen; Laine, Tanja M.; Haukka, Matti; Zeglio, Erica; Abdel-Magied, Ahmed F.; Siegbahn, Per E. M.; Meyer, Franc; Karkas, Markus D.; Johnston, Eric V.; Nordlander, Ebbe; Akermark, Bjorn
Abstract
The synthesis of two molecular iron complexes, a dinuclear iron(III,III) complex and a nonanuclear iron complex, based on the di-nucleating ligand 2,2'-(2-hydroxy-5-methyl-1,3-phenylene)bis(1H-benzo[d]imidazole-4-carboxylic acid) is described. The two iron complexes were found to drive the oxidation of water by the one-electron oxidant [Ru(bpy)(3)](3+).
Issue Date
2016
Status
published
Publisher
Royal Soc Chemistry
Journal
Dalton Transactions 
ISSN
1477-9234; 1477-9226

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