Room-Temperature Characterization of a Mixed-Valent mu-Hydroxodicopper(II,III) Complex
2016 | journal article. A publication with affiliation to the University of Göttingen.
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Room-Temperature Characterization of a Mixed-Valent mu-Hydroxodicopper(II,III) Complex
Isaac, J. A.; Gennarini, F.; Lopez, I.; Thibon-Pourret, A.; David, R.; Gellon, G. & Gennaro, B. et al. (2016)
Inorganic Chemistry, 55(17) pp. 8263-8266. DOI: https://doi.org/10.1021/acs.inorgchem.6b01504
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Details
- Authors
- Isaac, James A.; Gennarini, Federica; Lopez, Isidoro; Thibon-Pourret, Aurore; David, Rolf; Gellon, Gisele; Gennaro, Beatrice; Philouze, Christian; Meyer, Franc; Demeshko, Serhiy; Le Mest, Yves; Reglier, Marius; Jamet, Helene; Le Poul, Nicolas; Belle, Catherine
- Abstract
- Bis(mu-hydroxo)dicopper(II,II) bearing a naphthyridine-based ligand has been synthesized and characterized in the solid state and solution. Cyclic voltammetry at room temperature displays a reversible redox system that corresponds to the monoelectronic oxidation of the complex. Spectroscopic and time-resolved spectroelectrochemical data coupled to theoretical results support the formation of a charge-localized mixed-valent Cu-2(II,III) species.
- Issue Date
- 2016
- Status
- published
- Publisher
- Amer Chemical Soc
- Journal
- Inorganic Chemistry
- ISSN
- 1520-510X; 0020-1669
- Sponsor
- COST action [CM1003]; STSM grant; [ANR-13-BSO7-0018]
