Facile routes to abnormal-NHC-cobalt(II) complexes
2017 | journal article. A publication with affiliation to the University of Göttingen.
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- Authors
- Ghadwal, Rajendra S.; Lamm, Jan-Hendrik; Rottschaefer, Dennis; Schuermann, Christian J.; Demeshko, Serhiy
- Abstract
- Deprotonation of [IPrPh]I (1) with Co{N(SiMe3)(2)}(2) readily affords the abnormal N-heterocyclic carbene (aNHC) complex (aIPr(Ph))(2)CoI2 (2) (aIPr(Ph) = 1,3-bis(2,6-iPr(2)C(6)H(3))-2-phenyl-imidazol4-ylidene). Treatment of 1 with NaHBEt3 yields (aIPr(Ph)) BEt3 (3) that serves as an aNHC-transfer agent and yields (aIPr(Ph)) Co{N(SiMe3)(2)}(2) (4) on reaction with Co{N(SiMe3)(2)}(2).
- Issue Date
- 2017
- Status
- published
- Publisher
- Royal Soc Chemistry
- Journal
- Dalton Transactions
- ISSN
- 1477-9234; 1477-9226
