Ruthenium(II)-Catalyzed meta C-H Mono- and Difluoromethylations by Phosphine/Carboxylate Cooperation
2017 | journal article. A publication with affiliation to the University of Göttingen.
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Ruthenium(II)-Catalyzed meta C-H Mono- and Difluoromethylations by Phosphine/Carboxylate Cooperation
Ruan, Z.; Zhang, S.; Zhu, C.; Ruth, P. N.; Stalke, D. & Ackermann, L. (2017)
Angewandte Chemie International Edition, 56(8) pp. 2045-2049. DOI: https://doi.org/10.1002/anie.201611595
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Details
- Authors
- Ruan, Zhixiong; Zhang, S.; Zhu, Cuiju; Ruth, Paul Niklas; Stalke, Dietmar; Ackermann, Lutz
- Abstract
- Ruthenium(II)-catalyzed meta-selective C-H (di) fluoromethylation was accomplished by phosphine and carboxylate cooperation. The remote C-H functionalization was characterized by ample substrate scope, thereby setting the stage for meta-(di) fluoromethylation through facile C-H cleavage.
- Issue Date
- 2017
- Status
- published
- Publisher
- Wiley-v C H Verlag Gmbh
- Journal
- Angewandte Chemie International Edition
- ISSN
- 1521-3773; 1433-7851
- Sponsor
- European Research Council under European Community/ERC [307535]; CSC
