An open route to asymmetric substituted Al-Al bonds using Al(I)- and Al(III)-precursors
2017 | journal article. A publication with affiliation to the University of Göttingen.
Jump to: Cite & Linked | Documents & Media | Details | Version history
Cite this publication
An open route to asymmetric substituted Al-Al bonds using Al(I)- and Al(III)-precursors
Li, B.; Kundu, S.; Zhu, H.; Keil, H.; Herbst-Irmer, R.; Stalke, D. & Frenking, G. et al. (2017)
Chemical Communications, 53(17) pp. 2543-2546. DOI: https://doi.org/10.1039/c7cc00325k
Documents & Media
Details
- Authors
- Li, Bin; Kundu, Subrata; Zhu, Hongping; Keil, Helena; Herbst-Irmer, Regine; Stalke, Dietmar; Frenking, Gernot; Andrada, Diego M.; Roesky, Herbert W.
- Abstract
- The reaction of LAl: (L = HC[C(Me) N(Ar)](2), Ar = 2,6-iPr(2)C(6)H(3)) and cAAC:-> AlX3 (X = Cl, I) (cAAC = cyclic alkyl amino carbene) results in strikingly asymmetric Al(II)-Al(II) compounds LAl(X)-Al(X)(2)-cAAC [X = Cl (2a); I (2b)]. In these dialuminum(II) compounds the two Al atoms bear different ligand environments. For a detailed insight into the structures, theoretical calculations were carried out.
- Issue Date
- 2017
- Status
- published
- Publisher
- Royal Soc Chemistry
- Journal
- Chemical Communications
- ISSN
- 1364-548X; 1359-7345
