Lightest member of the basic carboxylate structural pattern: [Al-3(mu(3)-O)(mu-O2CCF3)(6)(THF)(3)][(Me3Si)(3)CAl(O2CCF3)(3)]center dot C7H8
2002 | journal article. A publication with affiliation to the University of Göttingen.
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Lightest member of the basic carboxylate structural pattern: [Al-3(mu(3)-O)(mu-O2CCF3)(6)(THF)(3)][(Me3Si)(3)CAl(O2CCF3)(3)]center dot C7H8
Hatop, H.; Ferbinteanu, M.; Roesky, H. W.; Cimpoesu, F.; Schiefer, M.; Schmidt, H. G. & Noltemeyer, M. (2002)
Inorganic Chemistry, 41(4) pp. 1022-+. DOI: https://doi.org/10.1021/ic010880y
Documents & Media
Details
- Authors
- Hatop, H.; Ferbinteanu, M.; Roesky, H. W.; Cimpoesu, F.; Schiefer, M.; Schmidt, H. G.; Noltemeyer, M.
- Abstract
- [Al-3(mu(3)-O)(mu-O2CCF3)(6)(THF)(3)][(Me3Si)(3)CAl( OC(O)CF3)(3)]-C7H8 is the first characterized mu3-oxo-trinuclear basic carboxylate of aluminum closing the gap of isomorphism with the transition metal analogues. The system is an excellent case study for the electronic structure approached by DFT-B3LYP calculations. The actual system proves that the oxo-trinuclear pattern is stabilized by the chemical hardness of oxygen donors and by highly symmetric intramolecular packing of the ligands.
- Issue Date
- 2002
- Status
- published
- Publisher
- Amer Chemical Soc
- Journal
- Inorganic Chemistry
- ISSN
- 1520-510X; 0020-1669
