Base free lithium-organoaluminate and the gallium congener: potential precursors to heterometallic assemblies
2007 | journal article. A publication with affiliation to the University of Göttingen.
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Base free lithium-organoaluminate and the gallium congener: potential precursors to heterometallic assemblies
Singh, S.; Chai, J.; Pal, A.; Jancik, V.; Roesky, H. W. & Herbst-Irmer, R. (2007)
Chemical Communications,(46) pp. 4934-4936. DOI: https://doi.org/10.1039/b712240c
Documents & Media
Details
- Authors
- Singh, Sanjay; Chai, Jianfang; Pal, Aritra; Jancik, Vojtech; Roesky, Herbert W.; Herbst-Irmer, Regine
- Abstract
- The first examples of base free lithium-organoaluminate and the corresponding gallium compound [LM(Me)OLi](3) (M = Al (3), Ga (4); L = HC{C(Me)N-2,6-iPr(2)C(6)H(3)}(2)) have been prepared by the reaction of Li[N(SiMe3)(2)] with the corresponding metal hydroxides LM(Me)OH (M = Al (1), Ga(2)); the oxygen atom in the M-O-Li fragment exists as oxide ion and is involved in the central Li3O3 six-membered ring formation.
- Issue Date
- 2007
- Status
- published
- Publisher
- Royal Soc Chemistry
- Journal
- Chemical Communications
- ISSN
- 1359-7345
