Synthesis and structural characterization of monomeric heterobimetallic oxides with a Ge(II)-O-M skeleton (M = Yb, Y)
2007 | journal article. A publication with affiliation to the University of Göttingen.
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Synthesis and structural characterization of monomeric heterobimetallic oxides with a Ge(II)-O-M skeleton (M = Yb, Y)
Yang, Y.; Roesky, H. W.; Jones, P. G.; So, C.-W.; Zhang, Z.; Herbst-Irmer, R. & Ye, H. (2007)
Inorganic Chemistry, 46(25) pp. 10860-10863. DOI: https://doi.org/10.1021/ic701262x
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Details
- Authors
- Yang, Y.; Roesky, Herbert W.; Jones, Peter G.; So, Cheuk-Wai; Zhang, Z.; Herbst-Irmer, Regine; Ye, Hongqi
- Abstract
- The germanium hydroxide complexes LGe(mu-O)M(THF)Cp(2) (M = Yb, 1; Y, 2; L = HC[C(Me)N(Ar)](2); Ar = 2,6-iPr(2)C(6)H(3)) were prepared by the reaction of LGeOH with Cp(3)M (M = Yb, Y) in THF at ambient temperature with the elimination of HCp. 1 and 2 are pale-yellow solids. Both compounds crystallize isotypically as monomers in a triclinic space group P (1) over bar (pseudo- merohedrally twinned, two independent molecules) and were found to be stable in the solid state and in solution at room temperature. The six-membered C(3)N(2)Ge rings in 1 and 2 display a boat conformation with the germanium and the gamma-C out-of-plane. The Ge-O-M skeleton exhibits a bent arrangement (angles 151-154 degrees). The (1)H NMR investigation of 2 confirmed that the solid-state structure is also found in solution.
- Issue Date
- 2007
- Status
- published
- Publisher
- Amer Chemical Soc
- Journal
- Inorganic Chemistry
- ISSN
- 0020-1669