Syntheses and characterizations of a series of novel Ln(6)Cu(24) clusters with amino acids as ligands
2004 | journal article. A publication with affiliation to the University of Göttingen.
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Syntheses and characterizations of a series of novel Ln(6)Cu(24) clusters with amino acids as ligands
Zhang, J.; Sheng, T. L.; Xia, S. Q.; Leibeling, G.; Meyer, F. ; Hu, S. M. & Fu, R. B. et al. (2004)
Inorganic Chemistry, 43(17) pp. 5472-5478. DOI: https://doi.org/10.1021/ic0497073
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Details
- Authors
- Zhang, J.; Sheng, T. L.; Xia, S. Q.; Leibeling, G.; Meyer, Franc ; Hu, S. M.; Fu, R. B.; Xiang, S. C.; Wu, X. T.
- Abstract
- With glycine or L-alanine as ligands, a series of novel 3d-4f heterometallic Ln(6)Cu(24) clusters with the formulas of [(SmCu24)-Cu-6(mu(3)-OH)(30)(Gly)(12)(Ac)(12)(ClO4)(H2O)(16)](ClO4)(9)(.)(OH)(2)(.)(H2O)(31) (1) and [Ln(6)Cu(24)(mu(3)-OH)(30)(Ala)(12)(Ac)(6)(ClO4)(H2O)(12)](.)(ClO4)(10)(.)(OH)(7)(.)(H2O)(34) (2(.)Ln) (Ln = Tb, Gd, Sm, and La) were synthesized by self-assembly, among which 1 and 2(.)Tb were characterized by X-ray structure analysis. The metal skeleton of the clusters may be described as a huge {Ln(6)Cu(12)} octahedron (constructed with 6 Ln(III) ions located at the vertices and 12 inner Cu-II ions located at the midpoints of the edges) connected by 12 additional Cu-II ions (every 2 are connected to 1 Ln(III) vertex). The temperature dependence of the magnetic susceptibilities of 2(.)Ln was investigated and was found to vary with the central rare-earth ions. Impedance spectroscopic measurements of 2(.)Ln reveal that they are ionic conductors.
- Issue Date
- 2004
- Status
- published
- Publisher
- Amer Chemical Soc
- Journal
- Inorganic Chemistry
- ISSN
- 0020-1669