Rhenium(V) oxo complexes with acetylacetone derived schiff bases: Structure and catalytic epoxidation
2007 | journal article. A publication with affiliation to the University of Göttingen.
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Rhenium(V) oxo complexes with acetylacetone derived schiff bases: Structure and catalytic epoxidation
Sachse, A.; Mosch-Zanetti, N. C.; Lyashenko, G.; Wielandt, J. W.; Most, K.; Magull, J. & Dall'Antonia, F. et al. (2007)
Inorganic Chemistry, 46(17) pp. 7129-7135. DOI: https://doi.org/10.1021/ic700381n
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Details
- Authors
- Sachse, Anna; Mosch-Zanetti, Nadia C.; Lyashenko, Ganna; Wielandt, J. Wolfram; Most, Kerstin; Magull, Joerg; Dall'Antonia, Fabio; Pal, Aritra; Herbst-Irmer, Regine
- Abstract
- Substitution reactions of rhenium(V) oxo precursors [ReOC13(PPh3)21 or [NBU4][ReOC141 with the bidentate acetylacetone-d e rived ketoamine ligands APOH = 4-anilino-3-penten-2-one, DPOH = 4-[2,6-dimethylanilino]-3penten-2-one, and MTPOH = 4-[2-(methylthio)anilinol-3-penten-2-one gave the complexes [ReO(APO)CI2(PPh3)] (1), [ReO(DPO)C]2(PPh3)] (2), and [NBU4][ReOLCI31 (3, L = APO; 4, L = DPO; 5, L = MTPO), respectively. All complexes exhibit only one ketoamino chelate, independent of the amount of ligand added to the rhenium precursors. The complexes were characterized by 1H and 13C NMR spectroscopy. X-ray crystal structures of the complexes 1, 2, 4, and 5, including that of MTPOH, were determined, revealing the trans position of the two oxygen atoms and the trans-CI,Cl conformation in 1 and 2, in contrast to most other rhenium complexes of this type where the cis-CI,Cl conformation is observed. Coordination of the potentially tridentate ligand MTPOH in 5 is bidentate with a dangling thioether substituent. Compound 2 shows catalytic activity in the oxidation of cis-cyclooctene with tertbuty1hydroperoxide.
- Issue Date
- 2007
- Status
- published
- Publisher
- Amer Chemical Soc
- Journal
- Inorganic Chemistry
- ISSN
- 1520-510X; 0020-1669