Templated assembly of a mu(6)-CO32- dodecanuclear lanthanum dibenzoylmethanide hydroxido cluster with concomitant formation of phenylglyoxylate

2007 | journal article. A publication with affiliation to the University of Göttingen.

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​Templated assembly of a mu(6)-CO32- dodecanuclear lanthanum dibenzoylmethanide hydroxido cluster with concomitant formation of phenylglyoxylate​
Andrews, P. C.; Beck, T.; Forsyth, C. M.; Fraser, B. H.; Junk, P. C.; Massi, M. & Roesky, P. W.​ (2007) 
Dalton Transactions,(48) pp. 5651​-5654​.​ DOI: https://doi.org/10.1039/b710534g 

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Authors
Andrews, Philip C.; Beck, Tobias; Forsyth, Craig M.; Fraser, Benjamin H.; Junk, Peter C.; Massi, Massimiliano; Roesky, Peter W.
Abstract
Reaction of LaCl3 and dibenzoylmethane (Ph(2)acacH) in methanol with an excess of triethylamine resulted in the unexpected formation of a dodecanuclear hydroxo-bridged La cluster templated by CO32- and phenylglyoxylate (Phgly), as determined by X-ray crystallography.
Issue Date
2007
Status
published
Publisher
Royal Soc Chemistry
Journal
Dalton Transactions 
ISSN
1477-9226

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