A Simple Synthesis of [(Cp Al)4] and Its Conversion to the Heterocubanes [(Cp AlSe)4] and [(Cp AlTe)4] (Cp = 5-C5(CH3)5)
1993 | journal article. A publication with affiliation to the University of Göttingen.
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A Simple Synthesis of [(Cp Al)4] and Its Conversion to the Heterocubanes [(Cp AlSe)4] and [(Cp AlTe)4] (Cp = 5-C5(CH3)5)
Schulz, S.; Roesky, H. W.; Koch, H.-J.; Sheldrick, G. M.; Stalke, D. & Kuhn, A. (1993)
Angewandte Chemie / International Edition, 32(12) pp. 1729-1731. DOI: https://doi.org/10.1002/anie.199317291
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Details
- Authors
- Schulz, Stephan; Roesky, Herbert W.; Koch, Hans-Joachim; Sheldrick, George M.; Stalke, Dietmar; Kuhn, Annja
- Abstract
- Al4Se4 and Al4Te4 cubes are the central structural units of the heterocubanes [(Cp AlSe)4] and [(Cp AlTe)4] 1 (structure shown on right). These compounds were formed by the reaction of the tetrameric AlI compound [(Cp Al)4] with elemental selenium and tellurium, respectively. The driving force of this smooth reaction is the conversion from AlI to AlIII. Cp = 5-C5Me5;
- Issue Date
- 1993
- Journal
- Angewandte Chemie / International Edition
- Language
- English
