Mössbauer and mass spectrometry support for iron( ii ) catalysts in enantioselective C–H activation
2019 | journal article. A publication with affiliation to the University of Göttingen.
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Mössbauer and mass spectrometry support for iron( ii ) catalysts in enantioselective C–H activation
Loup, J.; Parchomyk, T.; Lülf, S.; Demeshko, S.; Meyer, F.; Koszinowski, K. & Ackermann, L. (2019)
Dalton Transactions, 48(16) pp. 5135-5139. DOI: https://doi.org/10.1039/C9DT00705A
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Details
- Authors
- Loup, Joachim; Parchomyk, Tobias; Lülf, Stefan; Demeshko, Serhiy; Meyer, Franc; Koszinowski, Konrad; Ackermann, Lutz
- Abstract
- A combination of electrospray-ionization mass spectrometry and Mössbauer spectroscopy was used to investigate the species generated in situ in highly enantioselective Fe/NHC-catalyzed C–H alkylations. The findings indicate an organometallic iron( ii )–NHC species to be of key relevance in the asymmetric catalysis.
- Issue Date
- 2019
- Journal
- Dalton Transactions
- ISSN
- 1477-9226
- eISSN
- 1477-9234
- ISSN
- 1477-9226
- eISSN
- 1477-9234
- Language
- English
