Rhodaelectro-catalyzed chemo-divergent C–H activations with alkylidenecyclopropanes for selective cyclopropylations
2021 | journal article. A publication with affiliation to the University of Göttingen.
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Rhodaelectro-catalyzed chemo-divergent C–H activations with alkylidenecyclopropanes for selective cyclopropylations
Shen, Z.; Maksso, I.; Kuniyil, R.; Rogge, T. & Ackermann, L. (2021)
Chemical Communications, 57(30) pp. 3668-3671. DOI: https://doi.org/10.1039/D0CC08123J
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Details
- Authors
- Shen, Zhigao; Maksso, Isaac; Kuniyil, Rositha; Rogge, Torben; Ackermann, Lutz
- Abstract
- Herein, we report on selectivity control in C–H activations with alkylidenecyclopropanes (ACPs) for the chemo-selective assembly of cyclopropanes or dienes. Thus, unprecedented rhodaelectro-catalyzed C–H activations were realized with diversely decorated ACPs with a wide substrate scope and electricity as the sole oxidant.
- Issue Date
- 2021
- Journal
- Chemical Communications
- ISSN
- 1359-7345
- eISSN
- 1364-548X
- Language
- English