Rhodaelectro-catalyzed chemo-divergent C–H activations with alkylidenecyclopropanes for selective cyclopropylations

2021 | journal article. A publication with affiliation to the University of Göttingen.

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​Rhodaelectro-catalyzed chemo-divergent C–H activations with alkylidenecyclopropanes for selective cyclopropylations​
Shen, Z.; Maksso, I.; Kuniyil, R.; Rogge, T. & Ackermann, L.​ (2021) 
Chemical Communications57(30) pp. 3668​-3671​.​ DOI: https://doi.org/10.1039/D0CC08123J 

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Authors
Shen, Zhigao; Maksso, Isaac; Kuniyil, Rositha; Rogge, Torben; Ackermann, Lutz
Abstract
Herein, we report on selectivity control in C–H activations with alkylidenecyclopropanes (ACPs) for the chemo-selective assembly of cyclopropanes or dienes. Thus, unprecedented rhodaelectro-catalyzed C–H activations were realized with diversely decorated ACPs with a wide substrate scope and electricity as the sole oxidant.
Issue Date
2021
Journal
Chemical Communications 
ISSN
1359-7345
eISSN
1364-548X
Language
English

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