Dimere Alkalimetallbenzamidinate: Einfluß des Metallions auf die Struktur
1992 | Zeitschriftenartikel. Eine Publikation mit Affiliation zur Georg-August-Universität Göttingen.
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Dokumente & Medien
Details
- Autor(en)
- Stalke, Dietmar; Wedler, Michael; Edelmann, Frank T.
- Zusammenfassung
- The molecular structures of two N-silylated alkali metal benzamidinates, [MeC6H4C(NSiMe3)2-Li(THF)]2 1 and [PhC(NSiMe3)2Na(Et2O)]2·Et2O 2, have been determined by low temperature X-ray diffraction studies. Both compounds are dimeric in the solid state but the molecular structures are strongly influenced by the alkali metal used. The Na---Na distance in 2 is unusually short (274.1 pm). The preparation of K[PhC(NSiMe3)2] (3) is also described.
- Erscheinungsdatum
- 1992
- Zeitschrift
- Journal of Organometallic Chemistry
- Organisation
- Fakultät für Chemie
- Dateiformat
- application/pdf
- Sprache
- Deutsch