Two triorganostannate complexes synthesised from bis(cyclopentadienyl)tin(II); structural variation between [Mg(thf)6]2+2[Sn(3-C5H5)3]– and [Li(thf)4]+[Sn(C13H9)3]–(thf = tetrahydrofuran, C13H9= fluorenyl)
1993 | Zeitschriftenartikel. Eine Publikation mit Affiliation zur Georg-August-Universität Göttingen.
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Zitiervorschlag
Two triorganostannate complexes synthesised from bis(cyclopentadienyl)tin(II); structural variation between [Mg(thf)6]2+2[Sn(3-C5H5)3]– and [Li(thf)4]+[Sn(C13H9)3]–(thf = tetrahydrofuran, C13H9= fluorenyl)
Edwards, A. J.; Paver, M. A.; Raithby, P. R.; Russell, C. A.; Stalke, D. ; Steiner, A. & Wright, D. S. (1993)
Dalton Transactions,(9) pp. 1465-1466. DOI: https://doi.org/10.1039/DT9930001465
Dokumente & Medien
Details
- Autor(en)
- Edwards, Andrew J.; Paver, Michael A.; Raithby, Paul R.; Russell, Christopher A.; Stalke, Dietmar ; Steiner, Alexander; Wright, Dominic S.
- Zusammenfassung
- Nucleophilic addition of Mg(C5H5)2 to Sn(C5H5)2(1 : 2) in tetrahydrofuran (thf) gave [Mg(thf)6]2+ 2[Sn(3-C5H5)3]21 whereas the reaction of fluorenyllithium (2 or 3 equivalents) resulted in nucleophilic substitution of both C5H5 ligands and in the formation of [Li(thf)4]+[Sn(C13H9)3]–2; the anion of 1 is essentially planar whereas that in 2 has a distorted-pyramidal structure.
- Erscheinungsdatum
- 1993
- Zeitschrift
- Dalton Transactions
- Organisation
- Fakultät für Chemie
- Dateiformat
- application/pdf
- Sprache
- Englisch
