Comparison of the X-ray crystal structures of the sodium and potassium 2,4,6-tris(trifluoromethyl)phenoxides (RO–) and 2,4,6-tris(trifluoromethyl)benzenethiolates (RS–); [Na(OR)(thf)2]2, [K(OR)(thf)2(µ-thf)]2, [Na(SR)(thf)2·0.25thf]x and [K(SR)(thf)]x(thf = tetrahydrofuran)
1991 | journal article. A publication with affiliation to the University of Göttingen.
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Comparison of the X-ray crystal structures of the sodium and potassium 2,4,6-tris(trifluoromethyl)phenoxides (RO–) and 2,4,6-tris(trifluoromethyl)benzenethiolates (RS–); [Na(OR)(thf)2]2, [K(OR)(thf)2(µ-thf)]2, [Na(SR)(thf)2·0.25thf]x and [K(SR)(thf)]x(thf = tetrahydrofuran)
Brooker, S.; Edelmann, F. T. ; Kottke, T.; Roesky, T.; Sheldrick, G. M. ; Stalke, D. & Whitmire, K. H. (1991)
Journal of the Chemical Society. Chemical communications,(3) pp. 144-146. DOI: https://doi.org/10.1039/C39910000144
Documents & Media
Details
- Authors
- Brooker, Sally; Edelmann, Frank Thomas ; Kottke, Thomas; Roesky, Thomas; Sheldrick, George M. ; Stalke, Dietmar ; Whitmire, Kenton H.
- Abstract
- Na(OR)(thf)2]21, [K(OR)(thf)2(µ-thf)]22, [Na(SR)(thf)2·0.25thf]x3 and [K(SR)-(thf)]x4 were formed by the reaction of the appropriate combinations of 2,4,6-tris(trifluoromethyl)phenol (ROH) or 2,4,6-tris(trifluorornethyl)benzenethiol (RSH) with NaH or KH; compounds 1-4 have been characterised by NMR spectrosccpy and single crystal X-ray structure analysis, both phenoxides being dimeric whereas two distinct polymeric structural types are observed for the thiolates.
- Issue Date
- 1991
- Journal
- Journal of the Chemical Society. Chemical communications
- Organization
- Fakultät für Chemie
- File Format
- application/pdf
- Language
- English
