Electrooxidative o -carborane chalcogenations without directing groups: cage activation by copper catalysis at room temperature
2021 | journal article. A publication with affiliation to the University of Göttingen.
Jump to: Cite & Linked | Documents & Media | Details | Version history
Cite this publication
Electrooxidative o -carborane chalcogenations without directing groups: cage activation by copper catalysis at room temperature
Yang, L.; Jei, B. B.; Scheremetjew, A.; Yuan, B.; Stückl, A. C. & Ackermann, L. (2021)
Chemical Science, 12(39) pp. 12971-12976. DOI: https://doi.org/10.1039/D1SC02905C
Documents & Media
Details
- Authors
- Yang, Long; Jei, Becky Bongsuiru; Scheremetjew, Alexej; Yuan, Binbin; Stückl, A. Claudia; Ackermann, Lutz
- Abstract
- Copper-catalyzed electrochemical cage C–H chalcogenation of o -carboranes has been realized to enable the synthesis of various cage C-sulfenylated and C-selenylated o -carboranes.
Copper-catalyzed electrochemical direct chalcogenations of o -carboranes was established at room temperature. Thereby, a series of cage C-sulfenylated and C-selenylated o -carboranes anchored with valuable functional groups was accessed with high levels of position- and chemo-selectivity control. The cupraelectrocatalysis provided efficient means to activate otherwise inert cage C–H bonds for the late-stage diversification of o -carboranes.
Copper-catalyzed electrochemical cage C–H chalcogenation of o -carboranes has been realized to enable the synthesis of various cage C-sulfenylated and C-selenylated o -carboranes.
Copper-catalyzed electrochemical direct chalcogenations of o -carboranes was established at room temperature. Thereby, a series of cage C-sulfenylated and C-selenylated o -carboranes anchored with valuable functional groups was accessed with high levels of position- and chemo-selectivity control. The cupraelectrocatalysis provided efficient means to activate otherwise inert cage C–H bonds for the late-stage diversification of o -carboranes. - Issue Date
- 2021
- Journal
- Chemical Science
- ISSN
- 2041-6520
- eISSN
- 2041-6539
- Language
- English
