Prof. Dr. Herbert W. Roesky

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  • 2019 | Journal Article
    ​ ​A benzimidazolyl terpyridine-Fe 2+ system and its recognition driven molecular model of a traffic light​
    Sonkar, A. K.; Rai, A.; Tripathi, K.; Sharma, P.; Roesky, H. W. ; Drew, M. G. B. & Mishra, L.​ (2019) 
    Dalton Transactions, 48(1) pp. 158​-167​.​ DOI: https://doi.org/10.1039/C8DT03690J 
    ​Details  DOI 
  • 2019 | Book Chapter
    ​ ​Oxygen Effect in Heteromultimetallic Catalysis: Oxygen-Bridged Catalysts for Olefin Polymerization Process​
    Gurubasavaraj, P. M.; Roesky, H. W.  & Hosmane, N. S.​ (2019)
    In:​Colacot, T.; Sivakumar, V.​ (Eds.), Organometallics in Process Chemistry. Topics in Organometallic Chemistry pp. 271​-306. (Vol. 65). ​Springer. DOI: https://doi.org/10.1007/3418_2019_29 
    ​Details  DOI 
  • 2019 | Journal Article
    ​ ​Isolation of Transient Acyclic Germanium(I) Radicals Stabilized by Cyclic Alkyl(amino) Carbenes​
    Siddiqui, M. M.; Sarkar, S. K.; Sinhababu, S.; Ruth, P. N.; Herbst-Irmer, R. ; Stalke, D.   & Ghosh, M. et al.​ (2019) 
    Journal of the American Chemical Society, 141(5) pp. 1908​-1912​.​ DOI: https://doi.org/10.1021/jacs.8b13434 
    ​Details  DOI 
  • 2019 | Journal Article
    ​ ​Cyclic Alkyl(amino) Carbene-Stabilized Monoradicals of Organosilicon(IV) Compounds with Small Substituents​
    Li, W.; Kundu, S.; Köhler, C.; Li, J.; Dutta, S.; Yang, Z. & Stalke, D.  et al.​ (2019) 
    Organometallics, 38(9) pp. 1939​-1945​.​ DOI: https://doi.org/10.1021/acs.organomet.9b00041 
    ​Details  DOI 
  • 2019 | Journal Article
    ​ ​Alkylaluminum Complexes as Precatalysts in Hydroboration of Nitriles and Carbodiimides​
    Ding, Y.; Ma, X. ; Liu, Y.; Liu, W.; Yang, Z. & Roesky, H. W. ​ (2019) 
    Organometallics, 38(15) pp. 3092​-3097​.​ DOI: https://doi.org/10.1021/acs.organomet.9b00421 
    ​Details  DOI 
  • 2019 | Journal Article
    ​ ​HAlCl 2 and H 2 AlCl as Precursors for the Preparation of Compounds with Four- and Five-Coordinate Aluminum​
    Zhong, M.; Liu, Y.; Kundu, S.; Graw, N. ; Li, J.; Yang, Z. & Herbst-Irmer, R.  et al.​ (2019) 
    Inorganic Chemistry, 58(16) pp. 10625​-10628​.​ DOI: https://doi.org/10.1021/acs.inorgchem.9b02001 
    ​Details  DOI 
  • 2019 | Journal Article | 
    ​ ​Stable cyclic (alkyl)(amino)carbene (cAAC) radicals with main group substituents​
    Kundu, S.; Sinhababu, S.; Chandrasekhar, V. & Roesky, H. W. ​ (2019) 
    Chemical Science, 10(18) pp. 4727​-4741​.​ DOI: https://doi.org/10.1039/C9SC01351B 
    ​Details  DOI 
  • 2019 | Journal Article | 
    ​ ​(PhC(N t Bu) 2 Al) 2 (SiH 2 ) 4 six-membered heterocycle: comparable in structure to cyclohexane​
    Li, J.; Zhong, M.; Keil, H.; Zhu, H.; Herbst-Irmer, R. ; Stalke, D.   & De, S. et al.​ (2019) 
    Chemical Communications, 55(16) pp. 2360​-2363​.​ DOI: https://doi.org/10.1039/C8CC10124H 
    ​Details  DOI 
  • 2019 | Journal Article | 
    ​ ​Silylene induced cooperative B–H bond activation and unprecedented aldehyde C–H bond splitting with amidinate ring expansion​
    Swamy, V. S. V. S. N.; Raj, K. V.; Vanka, K.; Sen, S. S. & Roesky, H. W. ​ (2019) 
    Chemical Communications, 55(24) pp. 3536​-3539​.​ DOI: https://doi.org/10.1039/C9CC00296K 
    ​Details  DOI 
  • 2019 | Journal Article | 
    ​ ​Organoaluminum Compounds as Catalysts for Monohydroboration of Carbodiimides​
    Shen, Q.; Ma, X. ; Li, W.; Liu, W.; Ding, Y.; Yang, Z. & Roesky, H. W. ​ (2019) 
    Chemistry – A European Journal, 25(51) pp. 11918​-11923​.​ DOI: https://doi.org/10.1002/chem.201902000 
    ​Details  DOI 
  • 2019 | Journal Article | 
    ​ ​Treatment of Silylene–Phosphinidene with Chalcogens Resulted Exclusively in the Formation of Silicon‐Bonded Chalcogens​
    Sinhababu, S.; Siddiqui, M. M.; Sarkar, S. K.; Münch, A.; Herbst‐Irmer, R. ; George, A. & Parameswaran, P. et al.​ (2019) 
    Chemistry – A European Journal, 25(49) pp. 11422​-11426​.​ DOI: https://doi.org/10.1002/chem.201902661 
    ​Details  DOI 
  • 2018 | Journal Article
    ​ ​Synthesis of Cyclic Alkyl(amino) Carbene Stabilized Silylenes with Small N‐Donating Substituents​
    Li, W.; Köhler, C.; Yang, Z.; Stalke, D. ; Herbst‐Irmer, R.   & Roesky, H. W. ​ (2018) 
    Chemistry – A European Journal,.​ DOI: https://doi.org/10.1002/chem.201805267 
    ​Details  DOI 
  • 2018 | Journal Article
    ​ ​Carbene-Stabilized Exceptional Silicon Halides​
    Khan, S. & Roesky, H. W. ​ (2018) 
    Chemistry - A European Journal, 25(7) pp. 1636​-1648​.​ DOI: https://doi.org/10.1002/chem.201801672 
    ​Details  DOI 
  • 2018 | Journal Article
    ​ ​The chemistry of aluminum(I) with β-diketiminate ligands and pentamethylcyclopentadienyl-substituents: Synthesis, reactivity and applications​
    Liu, Y.; Li, J.; Ma, X. ; Yang, Z. & Roesky, H. W. ​ (2018) 
    Coordination Chemistry Reviews, 374 pp. 387​-415​.​ DOI: https://doi.org/10.1016/j.ccr.2018.07.004 
    ​Details  DOI 
  • 2018 | Journal Article
    ​ ​Self-Assembly of Discrete Copper(I)-Halide Complexes with Diacylthioureas​
    Hou, X.; Wang, F.; Han, L.; Pan, X.; Li, H.; Yang, Y. & Roesky, H. W. ​ (2018) 
    Zeitschrift für anorganische und allgemeine Chemie, 644(3) pp. 142​-148​.​ DOI: https://doi.org/10.1002/zaac.201700430 
    ​Details  DOI 
  • 2018 | Journal Article
    ​ ​A Route to Aluminumdiisocyanate and -diisothiocyanate from an Al(I) Precursor​
    Sinhababu, S.; Kundu, S.; Paesch, A. N.; Herbst-Irmer, R. ; Stalke, D.   & Roesky, H. W. ​ (2018) 
    European Journal of Inorganic Chemistry, 2018(20-21) pp. 2237​-2240​.​ DOI: https://doi.org/10.1002/ejic.201701347 
    ​Details  DOI 
  • 2018 | Journal Article
    ​ ​A Dicobalt Coordination Complex with a Short Cobalt-Cobalt Distance​
    Kumar, J.; Gorantla, N. V. T. S. M.; Roy, S.; Paesch, A. N.; Herbst-Irmer, R. ; Stalke, D.   & Anusha, C. et al.​ (2018) 
    ChemistrySelect, 3(28) pp. 8221​-8228​.​ DOI: https://doi.org/10.1002/slct.201801172 
    ​Details  DOI 
  • 2018 | Journal Article
    ​ ​Comparison of Two Phosphinidenes Binding to Silicon(IV)dichloride as well as to Silylene​
    Kundu, S.; Sinhababu, S.; Siddiqui, M. M.; Luebben, A. V.; Dittrich, B. ; Yang, T. & Frenking, G. et al.​ (2018) 
    Journal of the American Chemical Society, 140(30) pp. 9409​-9412​.​ DOI: https://doi.org/10.1021/jacs.8b06230 
    ​Details  DOI 
  • 2018 | Journal Article
    ​ ​N -Tosyl Hydrazone Precursor for Diazo Compounds as Intermediates in the Synthesis of Aluminum Complexes​
    Liu, Y.; Ma, X. ; Ding, Y.; Yang, Z. & Roesky, H. W. ​ (2018) 
    Organometallics, 37(21) pp. 3839​-3845​.​ DOI: https://doi.org/10.1021/acs.organomet.8b00518 
    ​Details  DOI 
  • 2018 | Journal Article
    ​ ​Geschichten des Silbers​
    Roesky, H. W. ​ (2018) 
    Chemie konkret, 25(5) pp. 196​-198​.​ DOI: https://doi.org/10.1002/ckon.v25.5 
    ​Details  DOI 
  • 2018 | Journal Article | 
    ​ ​Silicon-fluorine chemistry: from the preparation of SiF 2 to C–F bond activation using silylenes and its heavier congeners​
    Sen, S. S. & Roesky, H. W. ​ (2018) 
    Chemical Communications, 54(40) pp. 5046​-5057​.​ DOI: https://doi.org/10.1039/C8CC01816B 
    ​Details  DOI 
  • 2018 | Journal Article
    ​ ​A Route to Base Coordinate Silicon Difluoride and the Silicon Trifluoride Radical​
    Sinhababu, S.; Kundu, S.; Paesch, A. N.; Herbst-Irmer, R. ; Stalke, D. ; Fernández, I. & Frenking, G. et al.​ (2018) 
    Chemistry - A European Journal, 24(6) pp. 1264​-1268​.​ DOI: https://doi.org/10.1002/chem.201705773 
    ​Details  DOI 
  • 2018 | Journal Article
    ​ ​Silanylidene and Germanylidene Anions: Valence‐Isoelectronic Species to the Well‐Studied Phosphinidene​
    Siddiqui, M. M.; Sinhababu, S.; Dutta, S.; Kundu, S.; Ruth, P. N.; Münch, A. & Herbst‐Irmer, R.  et al.​ (2018) 
    Angewandte Chemie International Edition, 57(36) pp. 11776​-11780​.​ DOI: https://doi.org/10.1002/anie.201805936 
    ​Details  DOI 
  • 2017 | Journal Article
    ​ ​Synthesis and characterization of Lewis base stabilized mono- and di-organo aluminum radicals​
    Kundu, S.; Sinhababu, S.; Dutta, S.; Mondal, T.; Koley, D.; Dittrich, B.   & Schwederski, B. et al.​ (2017) 
    Chemical Communications, 53(76) pp. 10516​-10519​.​ DOI: https://doi.org/10.1039/C7CC06358J 
    ​Details  DOI 
  • 2017 | Journal Article
    ​ ​Different Reactivity of As 4 towards Disilenes and Silylenes​
    Seitz, A. E.; Eckhardt, M.; Sen, S. S.; Erlebach, A.; Peresypkina, E. V.; Roesky, H. W.   & Sierka, M. et al.​ (2017) 
    Angewandte Chemie International Edition, 56(23) pp. 6655​-6659​.​ DOI: https://doi.org/10.1002/anie.201701740 
    ​Details  DOI 
  • 2017 | Journal Article
    ​ ​Reversible C-H bond activation at a triosmium centre: A comparative study of the reactivity of unsaturated triosmium clusters Os 3 (CO) 8 (μ-dppm)(μ-H) 2 and Os 3 (CO) 8 (μ-dppf)(μ-H) 2 with activated alkynes​
    Chowdhury, M. A. H.; Haque, M. R.; Ghosh, S.; Mobin, S. M.; Tocher, D. A.; Hogarth, G. & Richmond, M. G. et al.​ (2017) 
    Journal of Organometallic Chemistry, 836-837 pp. 68​-80​.​ DOI: https://doi.org/10.1016/j.jorganchem.2017.02.041 
    ​Details  DOI 
  • 2017 | Journal Article
    ​ ​Organosilicon Radicals with Si–H and Si–Me Bonds from Commodity Precursors​
    Kundu, S.; Samuel, P. P. ; Sinhababu, S.; Luebben, A. V.; Dittrich, B. ; Andrada, D. M. & Frenking, G. et al.​ (2017) 
    Journal of the American Chemical Society, 139(32) pp. 11028​-11031​.​ DOI: https://doi.org/10.1021/jacs.7b06610 
    ​Details  DOI 
  • 2017 | Journal Article
    ​ ​Reagent for Introducing Base-Stabilized Phosphorus Atoms into Organic and Inorganic Compounds​
    Kundu, S.; Sinhababu, S.; Luebben, A. V.; Mondal, T.; Koley, D.; Dittrich, B.   & Roesky, H. W. ​ (2017) 
    Journal of the American Chemical Society, 140(1) pp. 151​-154​.​ DOI: https://doi.org/10.1021/jacs.7b11977 
    ​Details  DOI 
  • 2017 | Journal Article
    ​ ​Reactions of Ru 3 (CO) 10 (μ-dppm) with Ph 3 GeH: Ge–H and Ge–C bond cleavage in Ph 3 GeH at triruthenium clusters​
    Khan, M. M.; Alam, M.; Ghosh, S.; Rahaman, A.; Tocher, D. A.; Richmond, M. G. & Kabir, S. E. et al.​ (2017) 
    Journal of Organometallic Chemistry, 843 pp. 75​-86​.​ DOI: https://doi.org/10.1016/j.jorganchem.2017.05.003 
    ​Details  DOI 
  • 2017 | Journal Article
    ​ ​Soluble aluminum hydrides function as catalysts in deprotonation, insertion, and activation reactions​
    Li, W.; Ma, X. ; Walawalkar, M. G.; Yang, Z. & Roesky, H. W. ​ (2017) 
    Coordination Chemistry Reviews, 350 pp. 14​-29​.​ DOI: https://doi.org/10.1016/j.ccr.2017.03.017 
    ​Details  DOI 
  • 2017 | Journal Article
    ​ ​Facile Route to Rare Heterobimetallic Aluminum–Copper and Aluminum–Zinc Selenide Clusters​
    Li, B.; Li, J.; Liu, R.; Zhu, H. & Roesky, H. W. ​ (2017) 
    Inorganic Chemistry, 56(6) pp. 3136​-3139​.​ DOI: https://doi.org/10.1021/acs.inorgchem.7b00012 
    ​Details  DOI 
  • 2017 | Journal Article
    ​ ​A C(sp 2 )−H Dehydrogenation of Heteroarenes and Arenes by a Functionalized Aluminum Hydride​
    Chen, S.; Li, B.; Wang, X.; Huang, Y.; Li, J.; Zhu, H. & Zhao, L. et al.​ (2017) 
    Chemistry - A European Journal, 23(55) pp. 13633​-13637​.​ DOI: https://doi.org/10.1002/chem.201703804 
    ​Details  DOI 
  • 2017 | Journal Article
    ​ ​Two Structurally Characterized Conformational Isomers with Different C−P Bonds​
    Roy, S.; Mondal, K. C.; Kundu, S.; Li, B.; Schürmann, C. J.; Dutta, S. & Koley, D. et al.​ (2017) 
    Chemistry - A European Journal, 23(50) pp. 12153​-12157​.​ DOI: https://doi.org/10.1002/chem.201702870 
    ​Details  DOI 
  • 2017 | Journal Article
    ​ ​Germanium and Tin Monoxides Trapped by Oxophilic Germylene and Stannylene Ligands​
    Gao, Y.; Yang, Y.; Zheng, W.; Su, Y.; Zhang, X. & Roesky, H. W. ​ (2017) 
    Inorganic Chemistry, 56(17) pp. 10220​-10225​.​ DOI: https://doi.org/10.1021/acs.inorgchem.7b00918 
    ​Details  DOI 
  • 2017 | Journal Article
    ​ ​Mixed main group transition metal clusters: Reactions of [Ru 3 (CO) 10 (μ-dppm)] with Ph 3 SnH​
    Khan, M. M. M.; Ghosh, S.; Hogarth, G.; Tocher, D. A.; Richmond, M. G.; Kabir, S. E. & Roesky, H. W. ​ (2017) 
    Journal of Organometallic Chemistry, 840 pp. 47​-55​.​ DOI: https://doi.org/10.1016/j.jorganchem.2017.03.052 
    ​Details  DOI 
  • 2015 | Journal Article
    ​ ​Carbene-Dichlorosilylene Stabilized Phosphinidenes Exhibiting Strong Intramolecular Charge Transfer Transition​
    Roy, S.; Stollberg, P.; Herbst-Irmer, R. ; Stalke, D. ; Andrada, D. M.; Frenking, G. & Roesky, H. W. ​ (2015) 
    Journal of the American Chemical Society, 137(1) pp. 150​-153​.​ DOI: https://doi.org/10.1021/ja512089e 
    ​Details  DOI  PMID  PMC  WoS 
  • 2014 | Journal Article
    ​ ​One-Electron-Mediated Rearrangements of 2,3-Disiladicarbene​
    Mondal, K. C.; Samuel, P. P. ; Roesky, H. W. ; Aysin, R. R.; Leites, L. A.; Neudeck, S. & Luebben, J. et al.​ (2014) 
    Journal of the American Chemical Society, 136(25) pp. 8919​-8922​.​ DOI: https://doi.org/10.1021/ja504821u 
    ​Details  DOI  PMID  PMC  WoS 
  • 2013 | Journal Article
    ​ ​Conversion of a Singlet Silylene to a stable Biradical​
    Mondal, K. C.; Roesky, H. W. ; Schwarzer, M. C.; Frenking, G.; Tkach, I.; Wolf, H. & Kratzert, D. et al.​ (2013) 
    Angewandte Chemie International Edition, 52(6) pp. 1801​-1805​.​ DOI: https://doi.org/10.1002/anie.201204487 
    ​Details  DOI  PMID  PMC  WoS 
  • 2013 | Journal Article
    ​ ​Reaction of N-Heterocyclic Silylenes with Thioketone: Formation of SiliconSulfur Three (Si-C-S)- and Five (Si-C-C-C-S)-Membered Ring Systems​
    Azhakar, R.; Ghadwal, R. S. ; Roesky, H. W. ; Mata, R. A. ; Wolf, H.; Herbst-Irmer, R.   & Stalke, D. ​ (2013) 
    Chemistry: a European Journal, 19(11) pp. 3715​-3720​.​ DOI: https://doi.org/10.1002/chem.201203242 
    ​Details  DOI  PMID  PMC  WoS 
  • 2012 | Journal Article
    ​ ​Monomeric Sn(II) and Ge(II) hydrides supported by a tridentate pincer-based ligand​
    Khan, S.; Samuel, P. P. ; Michel, R.; Dieterich, J. M.; Mata, R. A. ; Demers, J.-P. & Lange, A.  et al.​ (2012) 
    Chemical Communications, 48(40) pp. 4890​-4892​.​ DOI: https://doi.org/10.1039/c2cc31214j 
    ​Details  DOI  PMID  PMC  WoS 
  • 2011 | Journal Article
    ​ ​A Stable Cation of a CSi3P Five-Membered Ring with a Weakly Coordinating Chloride Anion​
    Sen, S. S.; Hey, J.; Eckhardt, M.; Herbst-Irmer, R. ; Maedl, E.; Mata, R. A.   & Roesky, H. W.  et al.​ (2011) 
    Angewandte Chemie International Edition, 50(52) pp. 12510​-12513​.​ DOI: https://doi.org/10.1002/anie.201104146 
    ​Details  DOI  PMID  PMC  WoS 
  • 2011 | Journal Article
    ​ ​Preparation of RSn(I)-Sn(I)R with Two Unsymmetrically Coordinated Sn(I) Atoms and Subsequent Gentle Activation of P-4​
    Khan, S.; Michel, R.; Dieterich, J. M.; Mata, R. A. ; Roesky, H. W. ; Demers, J.-P. & Lange, A.  et al.​ (2011) 
    Journal of the American Chemical Society, 133(44) pp. 17889​-17894​.​ DOI: https://doi.org/10.1021/ja207538g 
    ​Details  DOI  PMID  PMC  WoS 

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