A volatile cyclic metallaphosphazene; preparation and X-ray structure of [(CF3)2PN]2NVCl2

1989 | journal article. A publication with affiliation to the University of Göttingen.

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​A volatile cyclic metallaphosphazene; preparation and X-ray structure of [(CF3)2PN]2NVCl2​
Roesky, H. W. ; Olms, P.; Witt, M.; Keller, K.; Stalke, D. ; Henkel, T. & Sheldrick, G. M. ​ (1989) 
Journal of the Chemical Society. Chemical communications,(6) pp. 366​-367​.​ DOI: https://doi.org/10.1039/C39890000366 

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Authors
Roesky, Herbert W. ; Olms, Petra; Witt, Michael; Keller, Klaus; Stalke, Dietmar ; Henkel, Thomas; Sheldrick, George M. 
Abstract
The reaction of (CF3)2P(Cl)NSiMe3 and Me3SiNVCl3 in CH2Cl2 leads to volatile [(CF3)2PN]2NVCl2; the X-ray structure analysis shows a planar six-membered NVNPNP-ring with C2v molecular symmetry.
Issue Date
1989
Journal
Journal of the Chemical Society. Chemical communications 
Organization
Fakultät für Chemie 
File Format
application/pdf
Language
English

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