Thiazolium carbene catalysts for the fixation of CO2 onto amines
2016 | Zeitschriftenartikel. Eine Publikation mit Affiliation zur Georg-August-Universität Göttingen.
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Dokumente & Medien
Details
- Autor(en)
- Das, Shoubhik; Bobbink, Felix D.; Bulut, Safak; Soudani, Mylène; Dyson, Paul J.
- Zusammenfassung
- The catalytic N-formylation and N-methylation of amines using CO2 as the carbon source represents a facile and sustainable approach for the synthesis of pharmaceuticals and natural products. Herein, we describe highly effective and inexpensive thiazolium carbenebased catalysts derived from vitamin B1 for the N-formylation and N-methylation of amines, using polymethylhydrosiloxane (PMHS) as a reducing agent, which operate under ambient conditions.
- Erscheinungsdatum
- 2016
- Status
- published
- Herausgeber
- Royal Soc Chemistry
- Zeitschrift
- Chemical Communications
- Organisation
- Fakultät für Chemie
- ISSN
- 1364-548X; 1359-7345
- Sprache
- Englisch