Thiazolium carbene catalysts for the fixation of CO2 onto amines
2016 | journal article. A publication with affiliation to the University of Göttingen.
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Cite this publication
Das, Shoubhik, Felix D. Bobbink, Safak Bulut, Mylène Soudani, and Paul J. Dyson. "Thiazolium carbene catalysts for the fixation of CO2 onto amines." Chemical Communications 52, no. 12 (2016): 2497-2500. https://doi.org/10.1039/C5CC08741D.
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Details
- Authors
- Das, Shoubhik; Bobbink, Felix D.; Bulut, Safak; Soudani, Mylène; Dyson, Paul J.
- Abstract
- The catalytic N-formylation and N-methylation of amines using CO2 as the carbon source represents a facile and sustainable approach for the synthesis of pharmaceuticals and natural products. Herein, we describe highly effective and inexpensive thiazolium carbenebased catalysts derived from vitamin B1 for the N-formylation and N-methylation of amines, using polymethylhydrosiloxane (PMHS) as a reducing agent, which operate under ambient conditions.
- Issue Date
- 2016
- Status
- published
- Publisher
- Royal Soc Chemistry
- Journal
- Chemical Communications
- Organization
- Fakultät für Chemie
- ISSN
- 1364-548X; 1359-7345
- Language
- English
