A Square-Planar Osmium(II) Complex
2017 | journal article. A publication with affiliation to the University of Göttingen.
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A Square-Planar Osmium(II) Complex
Abbenseth, J.; Diefenbach, M.; Bete, S. C.; Würtele, C.; Volkmann, C.; Demeshko, S. & Holthausen, M. C. et al. (2017)
Chemical Communications, 53(40) pp. 5511-5514. DOI: https://doi.org/10.1039/C7CC01569K
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Details
- Authors
- Abbenseth, Josh; Diefenbach, Martin; Bete, Sarah C.; Würtele, Christian; Volkmann, Christian; Demeshko, Serhiy; Holthausen, Max C.; Schneider, Sven
- Abstract
- Reduction of the pincer complex [OsIIICl2(PNP)] (PNP = N(CHCHPtBu2)2) affords the isolation and full characterization of an osmium(II) complex with square-planar coordination geometry, i.e. [OsIICl(PNP)]. Spectroscopic, structural and magnetic data in combination with multireference computations indicate strong temperature independent paramagnetism, which arises from an energetically well separated ground state that mixes with excited states through spin-orbit coupling.
- Issue Date
- 2017
- Journal
- Chemical Communications
- Project
- info:eu-repo/grantAgreement/EC/H2020/646747/EU//N2FEED
- Organization
- Fakultät für Chemie
- ISSN
- 1359-7345
- eISSN
- 1364-548X
- Language
- English
