Ammonolysis of M-Cl bonds of organozirconium(IV) and titanium(III) chlorides in a liquid ammonia/toluene two phase system
2002 | journal article. A publication with affiliation to the University of Göttingen.
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Bai, G. C., Roesky, H. W. & Mueller, P. (2002). Ammonolysis of M-Cl bonds of organozirconium(IV) and titanium(III) chlorides in a liquid ammonia/toluene two phase system. BULLETIN OF THE POLISH ACADEMY OF SCIENCES-CHEMISTRY, 50(1), 1-10.
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Details
- Authors
- Bai, G. C.; Roesky, H. W. ; Mueller, P.
- Abstract
- Treatment of (MeC5H4)(2)ZrCl2 with K (Na) or NaNH2 in liquid ammonia/toluene at -78degreesC led to the pentanuclear zirconium cluster [{(MeC5H4)Zr}(5)(mu(5) - N)(mu(3) - NH)(4)(mu - NH2)(4)] (1) and the alkali metal aggregate [(MeC5H4)M](n) (M = K (2) or Na). Reaction of Cp-2 TiCl with NaNH2 in liquid ammonia/toluene at -78degreesC yielded Cp-2 TiNH2 (3).
- Issue Date
- 2002
- Journal
- BULLETIN OF THE POLISH ACADEMY OF SCIENCES-CHEMISTRY
- ISSN
- 0239-7285
