Monomeric Sn(II) and Ge(II) hydrides supported by a tridentate pincer-based ligand
2012 | journal article. A publication with affiliation to the University of Göttingen.
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Khan, Shabana, Prinson P. Samuel, Reent Michel, Johannes M. Dieterich, Ricardo A. Mata, Jean-Philippe Demers, Adam Lange, Herbert W. Roesky, and Dietmar Stalke. "Monomeric Sn(II) and Ge(II) hydrides supported by a tridentate pincer-based ligand." Chemical Communications 48, no. 40 (2012): 4890-4892. https://doi.org/10.1039/c2cc31214j.
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Details
- Authors
- Khan, Shabana; Samuel, Prinson P. ; Michel, Reent; Dieterich, Johannes M.; Mata, Ricardo A. ; Demers, Jean-Philippe; Lange, Adam ; Roesky, Herbert W. ; Stalke, Dietmar
- Abstract
- Herein we report the syntheses of terminal Sn(II) (3) and Ge(II) (4) hydrides from the corresponding chloride precursors [{2,6-iPr(2)C(6)H(3)NCMe}(2)C6H3MCl] (M = Sn (1), Ge (2)) using [K{B(sec-Bu)(3)}H] as a hydrogenating agent. Combination of steric shielding and intramolecular N -> M interactions resulted in the protection of M(II)-H bonds.
- Issue Date
- 2012
- Journal
- Chemical Communications
- ISSN
- 1359-7345
- eISSN
- 1364-548X
- Language
- English
