The position of deuterium in HOD-NNO as determined by structural and nuclear quadrupole coupling constants
2015-08-28 | journal article; research paper
Jump to: Cite & Linked | Documents & Media | Details | Version history
Cite this publication
Obenchain, Daniel A., Derek S. Frank, Stewart E. Novick, and William Klemperer. "The position of deuterium in HOD-NNO as determined by structural and nuclear quadrupole coupling constants." The Journal of Chemical Physics 143, no. 8 (2015): 084301. https://doi.org/10.1063/1.4928687.
Documents & Media
Details
- Authors
- Obenchain, Daniel A. ; Frank, Derek S.; Novick, Stewart E.; Klemperer, William
- Abstract
- Rotational spectra of the weakly bound H2O-N2O complex and its HOD-N2O isotopologue in a supersonic jet are reported. Rotational constants of the singly substituted deuterium in water and each singly substituted nitrogen-15 are presented. Combinations of isotopic data and high level ab initio calculations place the water in a similar position to those of the isoelectronic H2O-CO2 complex, with a slight tilt of the OH towards the NNO axis. The deuterium nuclear quadrupole coupling constant places the deuterium on the O-H axis quasi-parallel to the NNO axis.
- Issue Date
- 28-August-2015
- Journal
- The Journal of Chemical Physics
- ISSN
- 0021-9606
- eISSN
- 1089-7690
- Language
- English
